The 37-year-old's sublime display of power-hitting on Centre Court stopped Konta becoming the first British woman to make the final for 40 years and set up a title match against Spain's Garbine Muguruza.
The first set was tied, 4-4, but Williams displayed her ability to come up with the big point when she needed to, and she only grew more dominant as the match went on.
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Serena is missing Wimbledon, where she has won the last two titles and seven in total, as she prepares to become a mother for the first time. Williams will now be up against Garbine Muguruza, who defeated Slovakia's Magdalena Rybarikova 6-1, 6-1 earlier. Her nail-biting win against Simona Halep on Tuesday was seen by 7.4 million viewers, a record audience for a women's match at Wimbledon according to BBC figures. "She showed a lot of courage, played in tough situations against players who were in form", Williams said.
"I'm just surprised it's taken so long", Wade said. I'd like to think that I'm doing the same. I've been a part of some great moments and exciting moments in other events, as well. "I wanted to give them more, but I didn't and I was sad for them".
Williams had served significantly more double faults than Konta in the tournament prior to this match.
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"In that sense, in the way I feel my opponents have pushed me, and I in turn them, and to create such a, I guess, sporting excitement for the crowd, that makes it I think very special".
"In terms of how comfortable I felt out there and how focused I was on what I wanted to try and achieve out there, I felt really comfortable", Konta said.
Two of the three times Konta has won titles she has beaten Williams along the way, which could bode well this week. It's fine to be the last British women's victor at Wimbledon but it's better to have plenty of British players to win.
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While Konta struggled under the enormous pressure, Williams thrived as victor after winner came from her racket, piercing forehands particularly successful for the 10th seed.